Anatoly Melnikov

Anatoly Melnikov

he/him

Senior Researcher

Publications

You can also find my articles on my Google Scholar profile.

Journal Articles

Atomize: A Modular Software for Control and Automation of Scientific and Industrial Instruments

Published in Journal of Open Research Software, 2025

In this paper, an open sources software for control and automation of scientific and industrial instruments is described

Recommended citation: Melnikov A., Vedkal A., Ishchenko A., Veber S. "Atomize: A Modular Software for Control and Automation of Scientific and Industrial Instruments" J. Open Res. Softw. 2025. 13(1). Art. Num. 26.
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Application of pulsed heating in time-resolved EPR spectroscopy for longitudinal relaxation measurements

Published in The Journal of Chemical Physics, 2025

In this paper, we propose a new variant of transient (TR) EPR spectroscopy for measuring spin-lattice relaxation time in magnetically concentrated compounds

Recommended citation: Melnikov A.R., Maryasov A.G., Ishchenko A.S., Getmanov Y.V., Isaev N.P., Efimov N.N., Fedin M.V., Veber S.L. "Application of pulsed heating in time-resolved EPR spectroscopy for longitudinal relaxation measurements" J. Chem. Phys. 2025. 163(16). Art. Num. 164201.
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Thermomagnetic Bistability, Colossal Negative Thermal Expansion, and THz-Heat-Induced Switching in Cu-Nitroxide Complex

Published in Angewandte Chemie International Edition, 2025

In this paper, we report the first Cu(II)-nitroxide complex that exhibits TIESST-driven bistability up to 116 K

Recommended citation: Smirnova K., Golomolzina I., Fokin S., Tolstikov S., Chernavin P., Letyagin G., Romanenko G., Zaitsev K., Melnikov A., Veber S., Fedin M., Bogomyakov A. "Thermomagnetic Bistability, Colossal Negative Thermal Expansion, and THz-Heat-Induced Switching in Cu-Nitroxide Complex" Angew. Chem. Int. Ed. 2025. Art. Num. e202514043.
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Monitoring S=0 ↔ S=2 Spin-State Switching in Fe(II) Complex Using FT EPR and Trityl Radical as Local Magnetic Field Sensor

Published in Applied Magnetic Resonance, 2025

In this paper, we proposed a contactless spin probe to monitor spin crossover transitions in EPR-silent coordination compounds

Recommended citation: Borodulina A.V., Melnikov A.R., Samsonenko A.A., Rogozhnikova O.Yu., Tormyshev V.M., Fedin M.V., Veber S.L. "Monitoring S=0 ↔ S=2 Spin-State Switching in Fe(II) Complex Using FT EPR and Trityl Radical as Local Magnetic Field Sensor" Appl. Magn. Res. 2025. 56. P. 1535–1547.
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Inter-Kramers electric quadrupole transitions in high-spin systems induced by resonant alternating inhomogeneous electric field

Published in The Journal of Applied Physics, 2025

This theoretical paper compares E2 and M1 transitions in single-molecule magnets

Recommended citation: Maryasov A.G., Melnikov A.R., Fedin M.V., Veber S.L. "Inter-Kramers electric quadrupole transitions in high-spin systems induced by resonant alternating inhomogeneous electric field." J. Appl. Phys. 2025. 138(12). Art. Num. 123906.
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Paramagnetic Gas Adsorbed in Metal–Organic Framework: A Promising Platform for Spin Qubits Design

Published in The Journal of Physical Chemistry C, 2025

This paper is about nitric oxide (NO) in MOF-808 matrix

Recommended citation: Yazikova A.A., Tomilov A.S., Afimchenko N.A., Zilberberg I.L., Melnikov A.R., Smirnova K.A., Poryvaev A.S., Fedin M.V. "Paramagnetic Gas Adsorbed in Metal–Organic Framework: A Promising Platform for Spin Qubits Design." J. Phys. Chem. C. 2025. 129(17). P. 8455-8463.
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Temperature Dependence of the Sensitivity of PVDF Pyroelectric Sensors to THz Radiation: Towards Cryogenic Applications

Published in Sensors, 2024

We characterized the performance of the PVDF sensor at helium temperatures.

Recommended citation: Sinelnikov A.N., Melnikov A.R., Getmanov Y.V., Kolomeec D.A., Kalneus E.V., Fedin M.V., Veber S.L. "Temperature Dependence of the Sensitivity of PVDF Pyroelectric Sensors to THz Radiation: Towards Cryogenic Applications." Sensors. 2024. 24. Art. Num. 5808.
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Scalable Approach for Grafting Qubit Candidates onto the Surface of MOF-808 Framework

Published in Russian Journal of Coordination Chemistry, 2024

In this work a simple and scalable approach to obtain qubit candidates based on stable organic radical 3-carboxy-proxyl and MOF-808 framework was demonstrated

Recommended citation: Tomilov A.S., Yazikova A.A., Melnikov A.R., Smirnova K.A., Poryvaev A.S., Fedin M.V. "Scalable Approach for Grafting Qubit Candidates onto the Surface of MOF-808 Framework." Russ. J. Coord. Chem. 2024. 50(9). P. 646-652.
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Calculation of π Using a Molecular Electron Spin Qubit Implemented by Pulsed Electron Paramagnetic Resonance

Published in The Journal of Physical Chemistry Letters, 2024

This paper describes an interesting method to compare the performance of different mocelular electron spin qubits

Recommended citation: Borodulina A.V., Melnikov A.R., Bochkin G.A., Fedin M.V., Fel’dman, E.B., Veber S.L. "Calculation of π Using a Molecular Electron Spin Qubit Implemented by Pulsed Electron Paramagnetic Resonance." J. Phys. Chem. Lett. 2024. 15(31). P. 8026-8031.
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Inductive detection of temperature-induced magnetization dynamics of molecular spin systems

Published in The Journal of Chemical Physics, 2024

In this paper, we proposed an inductive detection of temperature-induced magnetization dynamics as applied to the study of molecular spin systems and describe the general design and construction of an induction probehead

Recommended citation: Melnikov A.R., Ivanov M.Y., Samsonenko A.A., Getmanov Y.V., Nikovskiy I.A., Matiukhina A.K., Zorina-Tikhonova E.N., Voronina J.K., Goloveshkin A.S., Babeshkin K.A., Efimov N.N., Kiskin M.A., Eremenko I.L., Fedin M.V., Veber S.L. "Inductive detection of temperature-induced magnetization dynamics of molecular spin systems ." J. Chem. Phys. 2024. 160(22). Art. Num. 224201.
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Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4

Published in High Energy Chemistry, 2023

The nature of the photoprocess of Nickel(II) Diselenophosphinate in CCl4 were determined y the EPR, steady-state and time-resolved optical spectroscopy methods

Recommended citation: Mikheylis A.V., Grivin V.P., Pozdnyakov I.P., Melnikov A.A., Melnikov A.R., Sadykov E.Kh., Artem’ev A.V. "Photophysics and Photochemistry of Nickel(II) Diselenophosphinate in CCl4." High Energy Chem. 2023. 57(3). P. S433-S440.
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Comparative Study of Single Crystal and Polymeric Pyroelectric Detectors in the 0.9–2.0 THz Range Using Monochromatic Laser Radiation of the NovoFEL

Published in Polymers, 2023

This work compares the performance of six different detectors, based on either LaTiO3 crystal or different polymeric films, using monochromatic radiation of the Novosibirsk Free Electron Laser facility (NovoFEL) in the frequency range of 0.9–2.0 THz

Recommended citation: Melnikov A.R., Kalneus E.V., Getmanov Y.V., Shevchenko D.A., Gerasimov V.V., Anisimov O.A., Fedin M.V., Veber S.L. "Comparative Study of Single Crystal and Polymeric Pyroelectric Detectors in the 0.9–2.0 THz Range Using Monochromatic Laser Radiation of the NovoFEL." Polymers. 2023. 15(20). Art. Num. 4124.
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Sensitivity optimization in pulse EPR experiments with photo-labels by multiple-echo-integrated dynamical decoupling

Published in Physical Chemistry Chemical Physics, 2023

In this paper, we demonstrate that the use of Carr–Parcel–Meiboom–Gill blocks followed by multiple echo integration is a promising route for sensitivity gain in pulsed EPR utilizing photo-excited triplet states

Recommended citation: Sannikova N.E., Melnikov A.R., Veber S.L., Krumkacheva O.A., Fedin M.V. "Sensitivity optimization in pulse EPR experiments with photo-labels by multiple-echo-integrated dynamical decoupling." Phys. Chem. Chem. Phys. 2023. 25(17). P. 11971-11980.
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A broadband pulse EPR spectrometer for high-throughput measurements in the X-band

Published in Journal of Magnetic Resonance Open, 2022

This paper describes a homemade X-band pulsed EPR spectrometer

Recommended citation: Isaev N.P., Melnikov A.R., Lomanovich K.A., Dugin M.V., Ivanov M.Y., Polovyanenko D.N., Veber S.L., Bowman M.K., Bagryanskaya E.G. "A broadband pulse EPR spectrometer for high-throughput measurements in the X-band." J. Magn. Res. Open. 2022. 14-15. Art. Num. 100092.
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The role of Heisenberg spin exchange and the quantum Zeno effect in the spin-selective reaction between spin-1/2 and spin-1 particles

Published in The Journal of Chemical Physics, 2022

This theoretical paper describes a kinetic model of the irreversible reaction between the spin-1/2 and spin-1 particles in an encounter complex with the reactive doublet state

Recommended citation: Bagryansky V.A., Melnikov A.R., Molin Y.N., Borovkov V.I. "The role of Heisenberg spin exchange and the quantum Zeno effect in the spin-selective reaction between spin-1/2 and spin-1 particles." J. Chem. Phys. 2023. 157(6). Art. Num. 064306.
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Temperature dynamics of magnetoactive compounds under terahertz irradiation: characterization by an EPR study

Published in Russian Chemical Bulletin, 2022

In this paper, we studied effects of powerful terahertz radiation on the spin state of Cu(II) based paramagnetic system

Recommended citation: Tumanov S.V., Melnikov A.R., Artiukhova N.A., Bogomyakov A.S., Shevchenko O.A., Getmanov Y.V., Ovcharenko V.I., Fedin M.V., Veber S.L. "Temperature dynamics of magnetoactive compounds under terahertz irradiation: characterization by an EPR study." Russ. Chem. Bull. 2022. 71(7). P. 1378-1384.
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Broadband multimodal THz waveguides for efficient transfer of high-power radiation in space-confined conditions

Published in Optics & Laser Technology, 2021

In this work, we present the design and fabrication of multimodal hollow THz waveguides used at the X-band Electron Paramagnetic Resonance endstation of the Novosibirsk Free Electron Laser facility

Recommended citation: Melnikov A.R., Samsonenko A.A., Getmanov Y.V., Shevchenko O.A., Shevchenko D.A., Stepanov A.A., Fedin M.V., Yurkin M.A., Veber S.L. "Broadband multimodal THz waveguides for efficient transfer of high-power radiation in space-confined conditions." Opt. Laser Technol. 2021. 143. Art. Num. 107375.
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Technical and software improvements of the EPR spectroscopy endstation at the NovoFEL facility: Status 2020

Published in AIP Conference Proceedings, 2020

In this work, the current status (2020) of the EPR endstation at the NovoFEL facility is described

Recommended citation: Melnikov A.R., Kiskin M.A., Getmanov Y.V., Shevchenko O.A., Fedin M.V., Veber S.L. "Technical and software improvements of the EPR spectroscopy endstation at the NovoFEL facility: Status 2020." AIP Conf. Proc. 2020. 2299(1). Art. Num. 030010.
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The Radiation Beamline of Novosibirsk Free-Electron Laser Facility Operating in Terahertz, Far-Infrared, and Mid-Infrared Ranges

Published in IEEE Transactions on Terahertz Science and Technology, 2020

In this work, we describe the 120-m beamline for transporting the radiation of the Novosibirsk FEL facility, consisting of three FELs of the terahertz (THz), far-infrared, and mid-infrared ranges

Recommended citation: Kubarev V.V., Sozinov G.I., Scheglov M.A., Vodopyanov A.V., Sidorov A.V., Melnikov A.R., Veber S.L. "The Radiation Beamline of Novosibirsk Free-Electron Laser Facility Operating in Terahertz, Far-Infrared, and Mid-Infrared Ranges." IEEE Trans. Terahertz Sci. Technol. 2020. 10(6). P. 634-646.
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Exploring the reactivity of b-cyclodextrin-encapsulated anthraquinone-2,6-disulfonate

Published in Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2020

The intracomplex reaction of anthraquinone-2,6-disulfonate in triplet excited state with beta-cyclodextrin and the reaction of 3AQDS:CD complex with external quencher, N-Acetyl-l-Tyrosine, have been studied using laser flash photolysis, 1H NMR and 1H CIDNP

Recommended citation: Babenko S.V., Melnikov A.R., Tsentalovich Y.P., Kruppa A.I. "Exploring the reactivity of b-cyclodextrin-encapsulated anthraquinone-2,6-disulfonate." J. Incl. Phenom. Macro. 2020. 97(1). P. 121-127.
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Electronic Modulation of the FEL-Oscillator Radiation Power Driven by ERL

Published in Proceedings of the 39th International Free-Electron Laser Conference, FEL 2019, 2019

In this work, we propose a simple way of fast control of the FEL lasing which is based on periodic phase shift of electron bunches with respect to radiation stored in optical cavity

Recommended citation: Shevchenko O.A., Bykov E.V., Fedin M.V., Getmanov Y.V., Melnikov A.R., Serednyakov S.S., Tararyshkin S.V., Veber S.L. "Electronic Modulation of the FEL-Oscillator Radiation Power Driven by ERL" Proc. FEL’19. 2019. 39. P. 98-101.
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Electronic Modulation of THz Radiation at NovoFEL: Technical Aspects and Possible Applications

Published in Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2019

In this work, we describe a pulsed mode of radiation generation for the NovoFEL

Recommended citation: Shevchenko O.A., Melnikov A.R., Tararyshkin S.V., Getmanov Y.V., Serednyakov S>S., Bykov E.V., Kubarev V.V., Fedin M.V., Veber S.L. "Electronic Modulation of THz Radiation at NovoFEL: Technical Aspects and Possible Applications" Materials. 2019. 12(19). Art. Num. 3063
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Water-soluble Re6-clusters with aromatic phosphine ligands – from synthesis to potential biomedical applications

Published in Inorganic Chemistry Frontiers, 2019

We present the syntheses of two new water-soluble hexarhenium cluster complexes with terminal amphiphilic phosphine ligands, and delineate their photoluminescence and X-ray excited optical luminescence (XEOL) properties

Recommended citation: Ivanov A.A., Konovalov D.I., Pozmogova T.N., Solovieva A.O., Melnikov A.R., Brylev K.A., Kuratieva N.V., Yanshole V.V., Kirakci K., Lang K., Cheltygmasheva S.N., Kitamura N., Shestopalova L.V., Mironov Y.V., Shestopalov M.A. "Water-soluble Re6-clusters with aromatic phosphine ligands – from synthesis to potential biomedical applications" Inorg. Chem. Front. 2019. 6(4). P. 882-892.
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Determination of Hyperfine Coupling Constants of Fluorinated Diphenylacetylene Radical Anions by Magnetic Field-Affected Reaction Yield Spectroscopy

Published in The Journal of Physical Chemistry A, 2018

In this work, the radical anions of two fluorinated diphenylacetylene derivatives with nonequivalent magnetic nuclei and unknown hyperfine coupling constants were investigated by MARY spectroscopy

Recommended citation: Sannikova V.A., Davydova M.P., Sherin P.S., Babenko S.V., Korolev V.V., Stepanov A.A., Nikul’shin, P.V., Kalneus E.V., Vasilevsky S.F., Benassi E., Melnikov A.R. "Determination of Hyperfine Coupling Constants of Fluorinated Diphenylacetylene Radical Anions by Magnetic Field-Affected Reaction Yield Spectroscopy" J. Phys. Chem. A. 2019. 123(2). P. 505-516.
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X-ray Generated Recombination Exciplexes of Substituted Diphenylacetylenes with Tertiary Amines: A Versatile Experimental Vehicle for Targeted Creation of Deep-Blue Electroluminescent Systems

Published in The Journal of Physical Chemistry A, 2018

In this work, we show that recombination exciplexes of simple substituted diphenylacetylenes with tertiary amines can be a convenient source of tunable deep-blue emission with possible applications in organic electroluminescent systems

Recommended citation: Melnikov A.R., Davydova M.P., Sherin P.S., Korolev V.V., Stepanov A.A., Kalneus E.V., Benassi E., Vasilevsky S.F., Stass D.V. "X-ray Generated Recombination Exciplexes of Substituted Diphenylacetylenes with Tertiary Amines: A Versatile Experimental Vehicle for Targeted Creation of Deep-Blue Electroluminescent Systems" J. Phys. Chem. A. 2018. 122(5). P. 1235-1252.
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A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes

Published in Dalton Transactions, 2017

This paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes

Recommended citation: Evtushok D.V., Melnikov A.R., Vorotnikova N.A., Vorotnikov Y.A., Ryadun A.A., Kuratieva N.V., Kozyr K.V., Obedinskaya N.R., Kretov E.I., Novozhilov I.N., Mironov Y.V., Stass D.V., Efremova O.A., Shestopalov M.A. "A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes" Dalton Trans. 2017. 46(35). P. 11738-11747.
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Estimation of the Fraction of Spin-Correlated Radical Ion Pairs in Irradiated Alkanes using Magnetosensitive Recombination Luminescence from Exciplexes Generated upon Recombination of a Probe Pair

Published in Zeitschrift für Physikalische Chemie, 2016

This paper describes the magnitude of magnetic field effects in exciplex emission formed by a novel acceptor-substituted diphenylacetylene and DMA

Recommended citation: Melnikov A.R., Verkhovlyuk V.N., Kalneus E.V., Korolev V.V., Borovkov V.I., Sherin P.S., Davydova M.P., Vasilevsky S.F., Stass D.V. "Estimation of the Fraction of Spin-Correlated Radical Ion Pairs in Irradiated Alkanes using Magnetosensitive Recombination Luminescence from Exciplexes Generated upon Recombination of a Probe Pair" Z. Phys. Chem. 2016. 231(2). P. 239-267.
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Estimation of the fluorescence lifetime for optically inaccessible exciplexes in nonpolar solutions under ionizing irradiation

Published in Photochemical Photobiological Sciences, 2016

In this paper, we present a simple and universal experimental approach for the estimation of fluorescence lifetimes of X-radiation generated exciplexes

Recommended citation: Melnikov A.R., Kalneus E.V., Korolev V.V., Sherin P.S., Borovkov V.I., Stass D.V. "Estimation of the fluorescence lifetime for optically inaccessible exciplexes in nonpolar solutions under ionizing irradiation" Photochem. Photobiol. Sci. 2016. 15(6). P. 767-778.
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Effect of ionizing radiation on the luminescence of mycelium of luminous fungus Neonothopanus nambi

Published in Biochemistry, Biophysics and Molecular Biology, 2014

In this paper, we report the effect of X-irradiation on the luminescence of fungus Neonothopanus nambi

Recommended citation: Bondar V.S., Puzyr A.P., Burov A.E., Medvedeva S.E., Rodicheva E.K., Kobzeva T.V., Melnikov A.R., Karogodina T.Y., Zikirin S.B., Stass D.V., Molin Y.N., Gitelson J.I. "Effect of ionizing radiation on the luminescence of mycelium of luminous fungus Neonothopanus nambi" Dokl. Biochem. Biophys. 2015. 460(1). P. 30-33.
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Highly efficient exciplex formation via radical ion pair recombination in X-irradiated alkane solutions for luminophores with short fluorescence lifetimes

Published in Photochemical Photobiological Sciences, 2014

In this paper, we shows a possibility of exciplex formation via irreversible recombination of radical ion pairs generated by X-irradiation of alkane solutions of N,N-dimethylaniline with various organic luminophores

Recommended citation: Melnikov A.R., Kalneus E.V., Korolev V.V., Dranov I.G., Kruppa A.I., Stass D.V. "Highly efficient exciplex formation via radical ion pair recombination in X-irradiated alkane solutions for luminophores with short fluorescence lifetimes" Photochem. Photobiol. Sci. 2014. 13(8). P. 1169-1179.
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Stimulation of luminescence of mycelium of luminous fungus Neonothopanus nambi by ionizing radiation

Published in Luminescence, 2014

In this work, we report the effect of X-irradiation on the luminescence of fungus Neonothopanus nambi. Application of X-rays does not change the emission spectrum, but after approximately 20 min of continuous irradiation, light production from unsupported mycelium starts growing

Recommended citation: Kobzeva T.V., Melnikov A.R., Karogodina T.Y., Zikirin S.B., Stass D.V., Molin Y.N., Rodicheva E.K., Medvedeva S.E., Puzyr A.P., Burov A.A., Bondar V.S., Gitelson J.I. "Stimulation of luminescence of mycelium of luminous fungus Neonothopanus nambi by ionizing radiation" Luminescence. 2014. 29(7). P. 703-710.
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Exciplex formation upon recombination of radiation-generated radical ion pairs in nonpolar solutions

Published in Doklady Physical Chemistry, 2013

In this work, we studied photo and radiation induced luminescence spectra of solutions of some donor–acceptor systems widely used in the radiation spin chemistry experiments, in particular, anthracene-DMA, p-terphenyl-DMA, and similar systems

Recommended citation: Melnikov A.R., Kalneus E.V., Korolev V.V., Dranov I.G., Stass D.V. "Exciplex formation upon recombination of radiation-generated radical ion pairs in nonpolar solutions" Dokl. Phys. Chem. 2013. 452(2). P. 257-260.
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Registration of radical anions of Al, Ga, In tris-8-oxyquinolinates by magnetosensitive and spectrally resolved recombination luminescence in benzene solutions

Published in Chemical Physics Letters, 2012

In this paper, we studied the formation and recombination of transient radical anions of Al, Ga, and In tris-8-oxyquinolinates

Recommended citation: Sergey N.V., Verkhovlyuk V.N., Kalneus E.V., Korolev V.V., Melnikov A.R., Burdukov A.B., Stass D.V., Molin Y.N. "Registration of radical anions of Al, Ga, In tris-8-oxyquinolinates by magnetosensitive and spectrally resolved recombination luminescence in benzene solutions" Chem. Phys. Lett. 2012. 442. P. 32-37.
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A Low-Field Magnetically Affected Reaction Yield (MARY) Spectrometer with Spectral Fluorescence Resolution

Published in Applied Magnetic Resonance, 2012

In this paper, a novel spectrometer for low-field studies in magnetically affected reaction yield (MARY) spectroscopy with fluorescence detection is described

Recommended citation: Kalneus E.V., Melnikov A.R., Korolev V.V., Ivannikov V.I., Stass D.V. "A Low-Field Magnetically Affected Reaction Yield (MARY) Spectrometer with Spectral Fluorescence Resolution" Appl. Magn. Res. 2013. 44(1). P. 81-96.
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The influence of coordination compounds on spin chemical processes in irradiated hydrocarbons

Published in Doklady Physical Chemistry, 2012

In this paper, we studied the effect of a coordination compound introduced into the sample on the MARY spectrum of a radical ion pair with known properties

Recommended citation: Sergey N.V., Stass D.V., Burdukov A.B., Melnikov A.R., Molin Y.N. "The influence of coordination compounds on spin chemical processes in irradiated hydrocarbons" Dokl. Phys. Chem. 2012. 442(1). P. 12-15.
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